|
|
S-adenosyl-L-methionine + kaempferol <=> H+ + S-adenosyl-L-homocysteine + kaempferide
|
2.1.1.155
kaempferol 4'-O-methyltransferase
2.1.1.231
flavonoid 4'-O-methyltransferase
|
–
–
|
MK
|
|
BRENDA:
BR48506
KEGG:
R06807
MetaCyc:
2.1.1.155-RXN
SABIO-RK:
6382
|
|
|
|
UDP-galactose + kaempferol <=> H+ + UDP + kaempferol_3-O-beta-D-galactoside
|
2.4.1.234
kaempferol 3-O-galactosyltransferase
|
–
|
MK
|
|
BRENDA:
BR48511
KEGG:
R06808
MetaCyc:
2.4.1.234-RXN
SABIO-RK:
8912
|
|
|
|
UDP-D-xylose + kaempferol <=> UDP + kaempferol_3-O-beta-D-xyloside + H+
|
2.4.2.56
kaempferol 3-O-xylosyltransferase
|
–
|
|
|
BRENDA:
BR50665
KEGG:
R10609
MetaCyc:
RXN-14702
|
|
|
|
UDP-glucose + kaempferol <=> H+ + kaempferol_7-O-glucoside + UDP
|
2.4.1.104
o-dihydroxycoumarin 7-O-glucosyltransferase
2.4.1.170
isoflavone 7-O-glucosyltransferase
2.4.1.185
flavanone 7-O-beta-glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
–
–
–
–
|
M
|
|
BRENDA:
BS321960
MetaCyc:
RXN-8263
|
|
|
|
UDP-glucose + kaempferol <=> kaempferol_3-O-glucoside + UDP + H+
|
2.4.1.115
anthocyanidin 3-O-glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.357
phlorizin synthase
2.4.1.91
flavonol 3-O-glucosyltransferase
|
–
–
–
–
|
MK
|
|
BRENDA:
BS323091
KEGG:
R06611
MetaCyc:
RXN1F-461
|
|
|
|
(+)-dihydrokaempferol + 2-oxoglutarate + O2 <=> kaempferol + succinate + CO2 + H2O + H+
|
1.14.20.5
flavone synthase I
1.14.20.6
flavonol synthase
|
–
–
|
MK
|
|
BRENDA:
BS371221;
BS373078
KEGG:
R03126
MetaCyc:
RXN1F-93
|
|
|
|
S-adenosyl-L-methionine + kaempferol <=> 3-O-methylkaempferol + S-adenosyl-L-homocysteine
|
2.1.1
2.1.1.76
quercetin 3-O-methyltransferase
|
–
–
|
M
|
|
BRENDA:
BS380271
KEGG:
R05035
MetaCyc:
RXN-13935
SABIO-RK:
4665
|
|
|
|
kaempferol + reduced_flavodoxin + O2 <=> quercetin + flavin + H2O
|
1.14.14.81
flavanoid 3',5'-hydroxylase
1.14.14.82
flavonoid 3'-monooxygenase
|
–
–
|
K
|
|
BRENDA:
BS288546
KEGG:
R06538
|
|
|
|
kaempferol + 2 reduced_flavodoxin + 2 O2 <=> 5,7,3'',4'',5''-pentahydroxyflavone + 2 flavin + 2 H2O
|
1.14.14.81
flavanoid 3',5'-hydroxylase
|
–
|
K
|
|
BRENDA:
BS388957
KEGG:
R10260
|
|
|
|
UDP-L-rhamnose + kaempferol <=> Afzelin + UDP + H+
|
2.4.1
|
–
|
MK
|
|
KEGG:
R09802
MetaCyc:
RXN1F-474
|
|
|
|
3''-phosphoadenylylsulfate + kaempferol <=> adenosine_3'',5''-bisphosphate + kaempferol_3-sulfate
|
2.8.2.25
flavonol 3-sulfotransferase
|
–
|
|
|
BRENDA:
BS359096
SABIO-RK:
12653
|
|
|
|
kaempferol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> quercetin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.82
flavonoid 3'-monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-12510
|
|
|
|
galangin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> kaempferol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
MetaCyc:
RXN66-595
|
|
|
|
kaempferide + reduced_[NADPH-hemoprotein_reductase] + O2 <=> kaempferol + oxidized_[NADPH-hemoprotein_reductase] + formaldehyde + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
MetaCyc:
RXN66-596
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> 3-O-methylkaempferol + kaempferol + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS421117
|
|
|
|
dihydrokaempferol + 2-oxoglutarate + O2 <=> kaempferol + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS373077
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> dihydrokaempferol + kaempferol + succinate + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS395072
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> (2R,3S)-cis-dihydrokaempferol + (2S,3S)-dihydrokaempferol + kaempferol + succinate + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS371266
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> (2R,3S)-cis-dihydrokaempferol + (+)-dihydrokaempferol + apigenin + kaempferol + succinate + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS371265
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> kaempferol + succinate + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
|
BRENDA:
BS371270
|
|
|
|
cis-dihydrokaempferol + 2-oxoglutarate + O2 <=> kaempferol + succinate + CO2 + H2O
|
1.14.20.5
flavone synthase I
1.14.20.6
flavonol synthase
|
–
–
|
|
|
BRENDA:
BS372733
|
|
|
|
kaempferol + reduced_flavodoxin + O2 <=> myricetin + flavin + H2O
|
1.14.14.81
flavanoid 3',5'-hydroxylase
|
–
|
|
|
BRENDA:
BS443664
|
|
|
|
UDP-glucuronate + kaempferol <=> UDP + kaempferol_7-O-beta-D-glucuronoside
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
|
BRENDA:
BS402145
|
|
|
|
S-adenosyl-L-methionine + kaempferol <=> 7-O-methylkaempferol
|
2.1.1.82
3-methylquercetin 7-O-methyltransferase
|
–
|
|
|
BRENDA:
BS421400
|
|
|
|
kaempferol_3-O-beta-D-glucuronide + H2O <=> kaempferol + D-glucuronate
|
3.2.1.31
beta-glucuronidase
|
–
|
|
|
BRENDA:
BS405519
|
|
|
|
S-adenosyl-L-methionine + kaempferol <=> S-adenosyl-L-homocysteine + 7-O-methylkaempferol
|
2.1.1.B75
2.1.1.B76
|
–
–
|
|
|
BRENDA:
BS419583
|
|
|
|
2 S-adenosyl-L-methionine + kaempferol <=> 2 S-adenosyl-L-homocysteine + kumatakenin
|
2.1.1.B75
2.1.1.B76
|
–
–
|
|
|
BRENDA:
BS419807
|
|
|
|
UDP-L-rhamnose + kaempferol <=> kaempferol-3-O-rhamnoside + UDP
|
2.4.1.159
flavonol-3-O-glucoside L-rhamnosyltransferase
|
–
|
|
|
BRENDA:
BS378172
|
|
|
|
UDP-glucose + kaempferol <=> UDP + 7-O-beta-D-glucosylkaempferol
|
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS322998
|
|
|
|
UDP-glucose + kaempferol <=> UDP + 4-O-beta-D-glucosyl-kaempferol
|
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS356097
|
|
|
|
3''-phosphoadenylylsulfate + kaempferol <=> adenosine_3'',5''-bisphosphate + kaempferol_sulfate
|
2.8.2.4
estrone sulfotransferase
|
–
|
|
|
BRENDA:
BS360504
|
|
|
|
adenosine_3''-phosphate_5''-phosphosulfate + kaempferol <=> adenosine_3'',5''-bisphosphate + kaempferol_7-sulfate
|
2.8.2.28
quercetin-3,3'-bissulfate 7-sulfotransferase
|
–
|
|
|
BRENDA:
BS387793
|
|
|
|
kaempferol_3-O-rutinoside + H2O <=> kaempferol + rutinose
|
3.2.1.B31
|
–
|
|
|
BRENDA:
BS423705
|
|